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李栋

发布时间:2020-04-11 阅读人数:

导师姓名:李栋

导师类型:硕士生导师

出生日期:1983/9/12

职称:教授(三级)

个人简介:

   日本北海道大学博士,英国牛津大学博士后,湖北省计划特聘教授

所在学院:材料与化学工程学院

专业:化学工程与技术

研究方向:有机合成化学,金属有机化学,有机功能材料

主讲硕士生课程:高等有机化学;有机化合物结构分析;现代化工专题

主讲博士生课程:

科研项目:

1. 过渡金属催化的选择性烯丙基碳-氢键氟化反应研究,国家自然科学基金项目,2014-2016,主持。

2. 过渡金属催化的新型氟化反应研究,湖北省计划创新人才项目,2014-2018,主持。

3. 钯催化碳-氢键亲核氟化反应研究及其在含氟药物合成中的应用,药物合成与优化湖北省重点实验室开放基金重点项目,2017-2019,主持。

4. 以19-羟基雄烯二酮为原料合成替勃龙的工艺开发,企业委托项目,2017-2018,主持。

5. 以20-(羟甲基)孕甾烯酮(BA)为原料合成黄体酮的工艺开发,企业委托项目,2018-2019,主持。

6. 金属卤盐参与的惰性sp3杂化碳氢键氧化亲核卤化反应研究,国家自然科学基金项目,2018-2020,参与。

7. 绿色催化技术在卤化反应中的应用研究,湖北省自然科学基金项目,2016-2017,参与。

8. 纳米能源材料开发与基础研究,催化材料2011协同创新中心协作项目,2014-2017,参与。

9. 新型氟化石墨烯的制备及其在正电极材料中的应用研究,绿色轻工材料湖北省重点实验室开放基金项目,2017-2018,参与。

科研成果:

近年来代表性论文:

1.Zhao, R.; Yang, Y.; Wang, X.; Ren, P.; Zhang, Q.;* Li, D.* “An efficient nickel/silver co-catalyzed remote C–H amination of 8-aminoquinolines with azodicarboxylates at room temperature” RSC Adv. 2018, 8, 37064–37068.

2.Xiao, Z.; Li, J.; Yue, Q.; Zhang, Q.; Li, D.* “An efficient and atom-economical route to N-aryl amino alcohols from primary amines” RSC Adv. 2018, 8, 34304–34308.

3.Xiao, Z.; Shu, S.; Lin, Y.; Zhang, Q.; Ren, P.;* Li, D.* “Chelation-assisted C–N cross-coupling between picolinamides and aryl boronic acids under nickel catalysis” Asian J. Org. Chem. 2018, 7, 2053–2056.

4.Xiang, D.; Xia, L.; Zhang, Y.; Zhang, Q.;* Li, D.* “Remote oxidative C−H amidation of anilides with dibenzenesulfonimides under metal-free conditions” Synlett 2018, 29, 1400–1404.

5.Yue, Q.; Xiao, Z.; Kuang, Z.; Su, Z.; Zhang, Q.;* Li, D.* “Chelation-promoted efficient C–H/N–H cross dehydrogenative coupling between picolinamides and simple ethers under copper catalysis” Adv. Synth. Catal. 2018,360, 1193–1198.

6.Yue, Q.; Xiao, Z.; Ran, Z.; Yuan, S.; Zhang, Q.;* Li, D.* “Copper-catalyzed α-C–H amidation of simple ethers through C(sp3)–H/N–H cross dehydrogenative coupling” Org. Chem. Front. 2018, 5, 967–971.

7.Xiao, Z.; Yue, Q.; Ran, Z.; Zhang, Q.;* Li, D.* “Copper-promoted N-arylation of 8-acylaminoquinoline compounds”Chin. J. Org. Chem. 2018, 38, 1193–1198.

8.Yang, Y.; Yu, Y.; Wang, Y.; Zhang, Q.;* Li, D.* “Metal-free remote oxidative benzylic C–H amination of 4-methylanilides with N-fluorobenzenesulfonimide” Tetrahedron, 2018, 74, 1085–1091.

9.Zhang, C.; Yue, Q.; Xiao, Z.; Wang, X.; Zhang, Q.; Li, D.* “Synthesis of O-aroyl-N,N-dimethyl hydroxylamines through hypervalent iodine-mediated amination of carboxylic acids with N,N-dimethylformamide” Synthesis 2017, 49, 4303–4308.

10.Yue, Q.; Yang, T.; Yang, Y.; Zhang, C.; Zhang, Q.; Li, D.* “Divergent reactivity of (dacyloxyiodo)arenes under palladium catalysis: controlled allylic C–H acyloxylation and vinylic arylation” Asian J. Org. Chem. 2017, 6, 936–942.

11.Wang, Y.; Wang, Y.; Zhang, Q.;* Li, D.* “Site-selective oxidative C–H sulfonylation of 8-acylaminoquinolines and anilides under metal-free conditions” Org. Chem. Front. 2017, 4, 514–518.

12.Li, L.; Wang, Y.; Yang, T.; Zhang, Q.; Li, D.* “Palladium-catalyzed non-directed C–H benzoxylation of simple arenes with iodobenzene dibenzoates” Tetrahedron Lett. 2016, 57, 5859–5863.

13.Wang, Y.; Wang, Y.; Guo, Z.; Zhang, Q.;* Li, D.* “Metal-free oxidative C–H amination of 8-acylaminoquinolines and anilides with N-fluorobenzenesulfonimide” Asian J. Org. Chem. 2016, 5, 1438–1441.

14.Wang, Y.; Wang, Y.; Jiang, K.; Zhang, Q.;* Li, D.* “Transition-metal-free oxidative C5 C–H-halogenation of 8-aminoquinoline amides using sodium halides” Org. Biomol. Chem. 2016, 14, 10180–10184.

15.Yang, T.; Zhang, Y.; Cao, P.; Wang, M.; Li, L.; Li, D.*; Liao, J.* “Copper-catalyzed enantioselective conjugate addition of diethylzinc to acyclic enones with chiral sulfoxide-phosphine ligands” Tetrahedron, 2016, 72, 2707–2711.

16.Zhang, Q.; Wang, Y.; Yang, T.; Li, L.; Li, D.* “Palladium catalyzed ortho-C–H-acylation of 2-arylpyridines using phenylacetylenes and styrene epoxide” Tetrahedron Lett. 2016, 57, 90–94.

17.Zhang, Q.; Wang, Y.; Yang, T.; Li, L.; Li, D.* “Palladium catalyzed ortho-C–H-benzoxylation of 2-arylpyridines using iodobenzene dibenzoates” Tetrahedron Lett. 2015, 56, 6136–6141.

18.Sun, Y.; Yuan, S.; Xiong, K.; Hu, K.; Luo, Y.; Fan, M.; Li, D.* “Preparation and characterization of boron nitride/carbon fiber composite with high specific surface area” Int. J. Mat. Res. 2014, 105, 599–602.