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张谦

发布时间:2020-04-11 阅读人数:

导师姓名:张谦

导师类型:硕士生导师

出生日期:1986/5/29

职称:副教授

个人简介:

    2003/9 - 2007/7,郑州大学,应用化学,学士,导师:廖新成 教授

    2007/9 – 2010/7,郑州大学,有机化学,硕士,导师:廖新成 教授

    2010/9 – 2014/7,郑州大学,有机化学,博士,导师:吴养洁 院士

    2014/9 – 2017/9,湖北澳门各大游戏平台网址大学,化学与化工学院,讲师

    2017/9 至今,湖北澳门各大游戏平台网址大学,化学与化工学院,副教授

    2018-12至2019-07, 日本京都大学, 理学院化学研究科, 访问学者, 合作导师: Hideki Yorimitsu

所在学院:材料与化学工程学院

专业:化学工程与工艺

研究方向:应用有机化学

主讲硕士生课程:

主讲博士生课程:

科研项目:

1、国家自然科学基金青年科学基金项目,21702054,金属卤盐参与的惰性sp3杂化碳氢键氧化亲核卤化反应研究、2018-2020、24万元、在研、主持。

2、过渡金属催化的新型卤化反应研究,OPP2015YB02,省级重点实验室项目,2015/09至2017/09,2.0万元,结题,主持。

3、以19-羟基雄烯二酮为原料合成替勃龙的工艺开发,横向,2016-2019,20.0万元,结题,参与。

4、绿色催化技术在卤化反应中的应用研究,00010,湖北省科技厅项目,2016/01至2017/12,3.0万元,结题,主持。

科研成果:

1. Qiang Yue, Zhen Xiao, Zhengkun Kuang, Zhengding Su, Qian Zhang,* and Dong Li,* “Chelation-promoted efficient C–H/N–H cross dehydrogenative coupling between picolinamides and simple ethers under copper catalysis” Adv. Synth. Catal., 2018, 360, 1193.

2. Qiang Yue, Zhen Xiao, Ziyao Ran, Songdong Yuan, Qian Zhang* and Dong Li*, “Copper-catalyzed α-C–H amidation of simple ethers through C(sp3)–H/N–H cross dehydrogenative coupling” Org. Chem. Front., 2018, 5, 967.

3. Yaocheng Yang, Yanting Yu, Yang Wang, Qian Zhang*, Dong Li*“Metal-free remote oxidative benzylic C–H amination of 4-methylanilides with N-fluorobenzenesulfonimide” Tetrahedron 2018, 74 1085.

4. Dehu Xiang, Lan Xia, Yunhua Zhang, Qian Zhang*, Dong Li *, “Remote oxidative C−H amidation of anilides with dibenzenesulfonimides under metal-free conditions” Synlett., 2018, 29, 1400.

5. Yang Wang, Ying Wang, Qian Zhang* and Dong Li*,“Site-selective oxidative C–H sulfonylation of 8-acylaminoquinolines and anilides under metal-free conditions” Org. Chem. Front., 2017, 4, 514.

6. Qiang Yue, Tingting Yang, Yaocheng Yang, Chuancheng Zhang, Qian Zhang, and Dong Li*,“Metal-free oxidative C–H amination of 8-acylaminoquinolines and anilides with N-fluorobenzenesulfonimide” Asian J. Org. Chem., 2017, 6, 936.

7. Chuancheng Zhang, Qiang Yu, Zhen Xiao, Xianglan Wang, Qian Zhang and Dong Li*, “Synthesis of O-aroyl-N,N-dimethyl hydroxylamines through hypervalent iodine-mediated amination of carboxylic acids with N,N-dimethylformamide” Synthesis 2017, 49, A.

8. Yang Wang, Ying Wang, Zhenyu Guo, Qian Zhang* and Dong Li*, “Metal-free oxidative C–H amination of 8-acylaminoquinolines and anilides with N-fluorobenzenesulfonimide” Asian J. Org. Chem., 2016, 5, 1438.

9. Qian Zhang, Yang Wang, Tingting Yang, Li Li, Dong Li*,“Palladium catalyzed ortho-C–H-acylation of 2-arylpyridines using phenylacetylenes and styrene epoxide” Tetrahedron Lett., 2016, 57, 90.

10. Ying Wang, Yang Wang, Kai Jiang, Qian Zhang* and Dong Li*, “Transition-metal-free oxidative C5 C–H-halogenation of 8-aminoquinoline amides using sodium halides” Org. Biomol. Chem., 2016, 14, 10180.

11. Li Li, Ying Wang, Tingting Yang, Qian Zhang and Dong Li*, “Palladium-catalyzed non-directed C–H benzoxylation of simple arenes with iodobenzene dibenzoates” Tetrahedron Lett., 2016, 57, 5859.

12. Guodong Zhang, Suyan Sun,a Fan Yang,* Qian Zhang, Jianxun Kang, Yusheng Wu,* and Yangjie Wua,* “Arylmethyl chlorides: new bifunctional reagents for palladium-catalyzed ortho-chlorination and acylation of 2-arylpyridines” Adv. Synth. Catal., 2015, 357, 443.

13. Qian Zhang, Ying Wang, Tingting Yang, Li Li, Dong Li*, “Palladium catalyzed ortho-C–H-benzoxylation of 2-arylpyridines using iodobenzene dibenzoates” Tetrahedron Lett., 2015, 56, 6136.

14. Qian Zhang, Fan Yang*, Yangjie Wu*,“DDQ: the chlorinating reagent and oxidant for the ligand-directed ortho-chlorination of 2-arylpyridines” Org. Chem. Front., 2014, 1, 694.

15. Qian Zhang, Chao Li, Fan Yang*, Jingya Li, Yangjie Wu*, “Palladium-catalyzed ortho-acylation of 2-arylbenzoxazoles” Tetrahedron 2013, 69, 320.

16. Qian Zhang, Fan Yang*, Yangjie Wu*, “Palladium-catalyzed ortho-acylation of 2-arylbenzoxazoles and 2-arylbenzothiazoles using arylmethyl alcohols as the acyl source” Tetrahedron 2013, 69, 4908.

17. Qian Zhang, Fan Yang*, Yangjie Wu*, “Palladium-catalyzed ortho-acylation of 2-aryl pyridine derivatives using arylmethyl amines as new acyl sources” Chem. Commun., 2013, 49, 6837.